Thermal reaction of a columnar assembled diacetylene macrocycle

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dc.contributor.authorXu, Yuewen
dc.contributor.authorSmith, Mark D
dc.contributor.authorArief C, Wibowo
dc.contributor.authorETAL..
dc.date.accessioned2022-01-08T14:58:37Z
dc.date.accessioned2023-08-19T09:06:05Z
dc.date.available2022-01-08T14:58:37Z
dc.date.available2023-08-19T09:06:05Z
dc.date.issued2010-04
dc.descriptionReported is a macrocyclic diacetylene that assembled into columns to afford porous crystals. Heating this assembly initiated a topochemical polymerization of the preorganized diacetylene units to give covalent conjugated polydiacetylenes. These stable conjugated materials maintained permanent porosity as evidenced by their type I gas adsorption isotherms with CO2 (g). Such conjugated polymeric nanotubes could possess unusual properties for sensing and electronics.en_US
dc.description.abstractReported is a macrocyclic diacetylene that assembled into columns to afford porous crystals. Heating this assembly initiated a topochemical polymerization of the preorganized diacetylene units to give covalent conjugated polydiacetylenes. These stable conjugated materials maintained permanent porosity as evidenced by their type I gas adsorption isotherms with CO2 (g). Such conjugated polymeric nanotubes could possess unusual properties for sensing and electronics.en_US
dc.identifier.citationXu, Y., Smith, M. D., Geer, M. F., Pellechia, P. J., Brown, J. C., Wibowo, A. C., & Shimizu, L. S. (2010). Thermal reaction of a columnar assembled diacetylene macrocycle. Journal of the American Chemical Society, 132(15), 5334-5335.en_US
dc.identifier.doihttps://doi.org/10.1021/ja9107066
dc.identifier.urihttps://edms.wexl.in/handle/1/2204
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.subjectThermal Reaction of a Columnaren_US
dc.subjectcolumns to afford porous crystalsen_US
dc.subjectcovalent conjugated polydiacetylenesen_US
dc.subjectSensing and electronicsen_US
dc.titleThermal reaction of a columnar assembled diacetylene macrocycleen_US
dc.title.alternativeJournal of the American Chemical Societyen_US
dc.typeArticleen_US

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