Thermal reaction of a columnar assembled diacetylene macrocycle

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Date

2010-04

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American Chemical Society

DOI

https://doi.org/10.1021/ja9107066

Abstract

Reported is a macrocyclic diacetylene that assembled into columns to afford porous crystals. Heating this assembly initiated a topochemical polymerization of the preorganized diacetylene units to give covalent conjugated polydiacetylenes. These stable conjugated materials maintained permanent porosity as evidenced by their type I gas adsorption isotherms with CO2 (g). Such conjugated polymeric nanotubes could possess unusual properties for sensing and electronics.

Keywords

Thermal Reaction of a Columnar , columns to afford porous crystals , covalent conjugated polydiacetylenes , Sensing and electronics

Citation

Xu, Y., Smith, M. D., Geer, M. F., Pellechia, P. J., Brown, J. C., Wibowo, A. C., & Shimizu, L. S. (2010). Thermal reaction of a columnar assembled diacetylene macrocycle. Journal of the American Chemical Society, 132(15), 5334-5335.

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Chemistry

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