New 3D bismuth-oxo coordination polymers containing terephthalate-based ligands: observation of Bi 2 O 2-layer and Bi 4 O 3-chain motifs

dc.contributor.authorSmith, Mark D
dc.contributor.authorzur Loye, Hans-Conrad
dc.contributor.authorArief C, Wibowo
dc.date.accessioned2022-01-08T15:19:27Z
dc.date.accessioned2023-08-19T09:06:07Z
dc.date.available2022-01-08T15:19:27Z
dc.date.available2023-08-19T09:06:07Z
dc.date.issued2011
dc.descriptionTwo new 3D framework materials containing Bi2O2 layers and Bi4O3 chains have been obtained hydrothermally via the reactions between bismuth nitrate with terephthalic acid (TA) and bismuth nitrate with nitro-terephthalic acid (NO2TA), respectively. The Bi2O2 layers are connected into a 3D structure via bridging TA ligands to form Bi2O2(TA) (1), while the novel Bi4O3 chains are connected into a 3D framework via linking NO2TA ligands to form Bi4O3(NO2TA)3(H2O)·(H2O)0.68 (2). Compound 1 exhibits photoluminescence that is red-shifted compared to that of the TA ligand, while the photoluminescence is quenched in both compound 2 and the NO2TA ligand.en_US
dc.description.abstractTwo new 3D framework materials containing Bi2O2 layers and Bi4O3 chains have been obtained hydrothermally via the reactions between bismuth nitrate with terephthalic acid (TA) and bismuth nitrate with nitro-terephthalic acid (NO2TA), respectively. The Bi2O2 layers are connected into a 3D structure via bridging TA ligands to form Bi2O2(TA) (1), while the novel Bi4O3 chains are connected into a 3D framework via linking NO2TA ligands to form Bi4O3(NO2TA)3(H2O)·(H2O)0.68 (2). Compound 1 exhibits photoluminescence that is red-shifted compared to that of the TA ligand, while the photoluminescence is quenched in both compound 2 and the NO2TA ligand.en_US
dc.identifier.citationWibowo, A. C., Smith, M. D., & zur Loye, H. C. (2011). New 3D bismuth-oxo coordination polymers containing terephthalate-based ligands: observation of Bi 2 O 2-layer and Bi 4 O 3-chain motifs. CrystEngComm, 13(2), 426-429.en_US
dc.identifier.doiDOI https://doi.org/10.1039/C0CE00650E
dc.identifier.urihttps://edms.wexl.in/handle/1/2209
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.subjectFramework materials containingen_US
dc.subjectBi2O2 layers and Bi4O3en_US
dc.subjectObtained hydrothermallyen_US
dc.titleNew 3D bismuth-oxo coordination polymers containing terephthalate-based ligands: observation of Bi 2 O 2-layer and Bi 4 O 3-chain motifsen_US
dc.title.alternativeCrystEngCommen_US
dc.typeArticleen_US

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