Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties
| dc.contributor.author | Smith, Mark D | |
| dc.contributor.author | Arief C, Wibowo | |
| dc.contributor.author | Yeon, Jeongho | |
| dc.contributor.author | ETAL.. | |
| dc.date.accessioned | 2022-01-08T17:07:24Z | |
| dc.date.accessioned | 2023-08-19T09:06:01Z | |
| dc.date.available | 2022-01-08T17:07:24Z | |
| dc.date.available | 2023-08-19T09:06:01Z | |
| dc.date.issued | 2012-11 | |
| dc.description | Two new 3D bismuth containing coordination polymers are reported along with their single crystal structures and SHG properties. Compound 1: Bi2O2(pydc) (pydc=pyridine-2, 5-dicarboxylate), crystallizes in the monoclinic, polar space group, P21 (a=9.6479(9) Å, b=4.2349(4) Å, c=11.9615(11) Å, β=109.587(1)°), which contains Bi2O2 chains that are connected into a 3D structure via the pydc ligands. Compound 2: Bi4Na4(1R3S-cam)8(EtOH)3.1(H2O)3.4 (1R3S cam=1R3S-camphoric acid) crystallizes in the monoclinic, polar space group, P21 (a=19.0855(7) Å, b=13.7706(5) Å, c=19.2429(7) Å, β=90.701(1)°) and is a true 3D coordination polymer. These are two example of SHG compounds prepared using unsymmetric ligands (compound 1) or chiral ligands (compound 2), together with metals that often exhibit stereochemically-active lone pairs, such as Bi3+, a synthetic approach that resulted in polar, non | en_US |
| dc.description.abstract | Two new 3D bismuth containing coordination polymers are reported along with their single crystal structures and SHG properties. Compound 1: Bi2O2(pydc) (pydc=pyridine-2, 5-dicarboxylate), crystallizes in the monoclinic, polar space group, P21 (a=9.6479(9) Å, b=4.2349(4) Å, c=11.9615(11) Å, β=109.587(1)°), which contains Bi2O2 chains that are connected into a 3D structure via the pydc ligands. Compound 2: Bi4Na4(1R3S-cam)8(EtOH)3.1(H2O)3.4 (1R3S cam=1R3S-camphoric acid) crystallizes in the monoclinic, polar space group, P21 (a=19.0855(7) Å, b=13.7706(5) Å, c=19.2429(7) Å, β=90.701(1)°) and is a true 3D coordination polymer. These are two example of SHG compounds prepared using unsymmetric ligands (compound 1) or chiral ligands (compound 2), together with metals that often exhibit stereochemically-active lone pairs, such as Bi3+, a synthetic approach that resulted in polar, non-centrosymmetric, 3D metal-organic coordination polymer. | en_US |
| dc.identifier.citation | Wibowo, A. C., Smith, M. D., Yeon, J., Halasyamani, P. S., & zur Loye, H. C. (2012). Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties. Journal of Solid State Chemistry, 195, 94-100. | en_US |
| dc.identifier.doi | https://doi.org/10.1016/j.jssc.2012.01.038 | |
| dc.identifier.uri | https://edms.wexl.in/handle/1/2214 | |
| dc.language.iso | other | en_US |
| dc.publisher | Academic Press | en_US |
| dc.subject | Coordination polymer | en_US |
| dc.subject | Polar structure | en_US |
| dc.subject | Second harmonic generation | en_US |
| dc.title | Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties | en_US |
| dc.title.alternative | Journal of Solid State Chemistry | en_US |
| dc.type | Article | en_US |
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