Zipping Up Diacetylene Macrocycles

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2010-07

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© Georg Thieme Verlag Stuttgart˙ New York

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Abstract

The topochemical polymerization of diacetylene macrocycle 1 is described. In the crystal 1 is stacked in columns organized by amide-amide hydrogen bonds. The arrangement provides optimal geometrical preconditions for a topochemical polymerization. Heating crystals of 1 induces changes that suggest the formation of polydiacetylenes.

Keywords

Diacetylene macrocycle , Polymerization. , Macrocycle

Citation

Xu, Y., Smith, M. D., Geer, M. F., Pellechia, P. J., Brown, J. C., Wibowo, A. C., & Shimizu, L. S. (2010). Zipping Up Diacetylene Macrocycles. Synfacts, 2010(07), 0775-0775.

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Chemistry

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